程瑞华，工学博士，副教授，硕士生导师。
联系电话：64253364
E‐mail：rhcheng@ecust.edu.cn
地址：上海市徐汇区梅陇路130 号beat365亚洲体育在线实验12 楼334 室
通讯方式：beat365亚洲体育在线, 上海市梅陇路130 号382 信箱 邮编：
200237

  研究方向：
（1）新型绿色聚烯烃催化剂的开发、机理研究及应用
（2）CO2 的高效转化和利用，聚（氨）酯的催化合成
主要科研项目：
目前正在承担的科研项目有国家自然科学基金，教育部基本科研业务费beat365亚洲体育在线探
索项目，企业横向项目一项，第二届“化工之星”优秀青年人才计划。同时作为技术负责人
与主要研究人员，参与20 余项国家、省部级及国内外企业横向项目，合作申请国家发明专
利6 项，在国内外发表学术论文30 余篇。
代表性论文：
1. Pengyuan Qiu, Ruihua Cheng, Zhen Liu, Boping Liu, Boris Tumanskii, Moris S. Eisen,
Switching from ethylene polymerization to nonselective oligomerization over a homogeneous
model catalyst: A triphenylsiloxy complex of chromium(VI) , Journal of Organometallic
Chemistry, 2012,699 , 48 -55.
2. Pengyuan Qiu, Ruihua Cheng, Boping Liu, Boris Tumanskii, Rami J. Batrice, Mark
Botoshansky, Moris S. Eisen, A Triphenylsiloxy Complex of Chromium(II) as a Switchable
Catalyst for Ethylene Polymerization and Nonselective Oligomerization, Organometallics,
2011, 30, 2144-2148.
3. Yun Yang, Zhen Liu, Lei Zhong, Pengyuan Qiu, Qi Dong, Ruihua Cheng, Jeffrey Vanderbilt,
Boping Liu, Spin surface crossing between chromium(I)/sextet and chromium(III)/quartet
without deprotonation in SNS-Cr mediated ethylene trimerization, Organometallics, 2011, 30
(19), 5297-5302.
4. Zhen Liu, Lei Zhong, Yun Yang, Ruihua Cheng, and Boping Liu, DFT and CASPT2 Study on
the Mechanism of ethylene dimerization over Cr(II)OH+ cation, Journal of Physical
Chemistry A, 2011, 115 (28), 8131-8141.
5. Ruihua Cheng, Chen Xu, Zhen Liu, Qi Dong, Xuelian He, Yuwei Fang, Minoru Terano, Yatao
Hu, Thomas J. Pullukat, Boping Liu*, High resolution spectroscopy (XPS, 1H MAS solid
state NMR) and DFT investigations on Ti-modified Phillips CrOx/SiO2 catalysts, Journal of
Catalysis, 2010, 273, 103-115.
6. Xiaofang Li, Ruihua Cheng∗, Jun Luo, Qi Dong, Xuelian He, Liuzhong Li, Yongling Yu,
Jianwen Da, Boping Liu*，Experimental and theoretical studies on ethylene polymerization
using SiO2-supported silyl chromate type catalysts prepared by a green method， Journal of
Molecular Catalysis A: Chemical， 2010，330，56-65.
7. Xiaochun Cao, Ruihua Cheng*, Zhen Liu, Lisong Wang, Qi Dong, Xuelian He, Boping Liu*,
DFT and PIO study of the influences of Mo valance state and surface hydroxyl on
supported-MoOx catalyst for ethylene polymerization, Journal of Molecular Catalysis A:
Chemical, 2010, 321, 50-60.
8. Ruihua Cheng, Zhen Liu, Pengyuan Qiu, Shiliang Zhang, Boping Liu*，Theoretical modeling
on the coordination mechanism of ethylene monomer on various prereduced Cr(II)Ox/SiO2
Phillips polyethylene model catalysts, Chinese Journal of Polymer Science, 2008, 26,
579-587.
9. Ruihua Cheng, Boping Liu*, Pengyuan Qiu, Shiliang Zhang, Zhen Liu, Toshiaki Taniike,
Minoru Terano, Mono- and di- ethylene coordination on a molecular cluster model of
prereduced Cr(II)Ox/SiO2 Phillips catalyst, Current Achivements on Heterogeneous Olefin
Polymerization Catalysts, edited by B. Liu and M. Terano, Sankeisha. Co., Ltd., Nagoya,
2008, 64-71.
10. Ruihua Cheng, Yuying Shu, Mingyuan Zheng, Lin Li, Jun Sun, Xiaodong Wang, Tao Zhang*,
Molybdenum phosphide, a new hydrazine decomposition catalyst: Microcalorimetry and
FTIR studies, Journal of Catalysis, 2007, 249, 397-400.
11. Ruihua Cheng, Lin Li, Mingyuan Zheng, Yuying Shu, Xiaodong Wang, Aiqin Wang, Tao
Zhang, Synthesis and characterization of high surface area molybdenum phosphide, Applied
Catalysis A: General, 2007, 316, 160-168.
12. Ruihua Cheng, Yuying Shu, Lin Li, Jun Sun, Xiaodong Wang, Tao Zhang*, Calorimetry
study of CO adsorption on highly dispersed MoP/Al2O3 prepared with citric acid,
Thermochimica Acta, 2006, 450, 42-46.
成果鉴定
参与的“十一五”国家科技支撑计划项目重点课题“己烯共聚PE100 级聚乙烯管材料研制及
产业化”已通过专家评审（鉴定号：中石化联鉴字[2011]第002 号）。
专利
1. 氧化铝改性硅胶负载型催化剂及其制备方法与应用，申请号CN20110170562.7，程瑞华，
徐建波，金栋梁，刘柏平。
2. 硅胶负载型复合铬系催化剂及其制备方法和应用，申请号CN 201010251149.9, 唐岩，
刘柏平，达建文，章施亮，谢侃，董奇, 程瑞华等。