姓名:刘振
职务:副教授
电话:021-64253364
手机:13816993351
电子邮件:liuzhen@ecust.edu.cn
教育背景:
2000.09~2004.06 郑州大学beat365亚洲体育在线 化学工程与工艺专业 学士学位
2005.09~2007.06 beat365亚洲体育在线 硕士在读 (导师,曾作祥教授)
2007.09~2013.03 beat365亚洲体育在线 博士学位 (导师,刘柏平教授)
2009.03~2009.09 瑞士联邦理工学院(ETH) 联合培养 (留学基金委资助,导师,Michele Parrinello教授)
工作经历:
2013.04~2015.05 beat365亚洲体育在线 师资博士后 (导师,钱锋教授)
2015.01~2016.12 比利时鲁汶大学(KU Leuven) 博士后 (2014年度博士后国际交流计划派出资助,合作导师,Jeremy Harvey教授)
2019.10~2020.08 澳大利亚国立大学访问学者 (2019年国家留学基金委公派访问学者项目资助,合作导师,Michelle Coote教授)
2013.04~至今 beat365亚洲体育在线 讲师,副教授(2018).
研究方向:
本人以第一/通讯作者在ACS Catalysis、Journal of Catalysis、 Catalysis Science &Technology、《有机化学》和《分子催化》等SCI及中文核心期刊上发表论文140余篇,被引2500余次(H-index:27)。主持了国家自然科学基金面上项目1项,上海市浦江人才计划A类项目1项,博士后国际合作项目1项,企业技术开发项目8项,获得中国专利授权6项,美国专利授权3项。
主要研究方向包括:
乙烯高选择性三聚、四聚催化剂及聚合反应工艺开发。在国家自然科学基金面上项目的资助下,针对乙烯选择性齐聚的关键科学问题,揭示了高选择性乙烯齐聚开关型催化剂的分子机制,建议了高碳α烯烃及聚乙烯副产物的形成机理,构建了乙烯选择性齐聚催化体系的机器学习模型。基于机器学习模型开发了乙烯齐聚性能可调的催化剂体系(CN115424682A)。
二氧化碳高值利用(CO2基聚碳酸酯及多元醇)。在上海市浦江人才计划A类项目资助下,解明了过渡金属催化CO2/C2H4偶联反应机理,特别是含铁、钌等体系在非绝热邻近势能面上进行的双态反应机理,建议了过渡金属催化CO2/C2H4偶联反应副产物的抑制方法,合成了一系列新型结构的NHC-P配体。该配体与传统的双氮、双膦配体的两步法反应机理不同,NHC-P配体可实现二氧化碳和乙烯经一步反应制备不饱和羧酸盐(CN115959987A),具有良好的工业应用前景。
其他方面,在特种聚酯合成、EVA光伏膜开发、PVB的合成及应用等方向均取得了重要的研究进展和一定的技术成果。
近年来发表SCI论文100余篇,被引用2000余次,谷歌学术H-index为28,i10-index为66,部分代表性论文如下:
1. Peng, J.; Mei, Y.; Chen, L.; Zhu, M.; Liu, Z.*, Computer-aided ligand screening to develop polymer-free catalyst in Cr-catalyzed ethylene oligomerization. Journal of Catalysis2024, 429. DOI: 10.1016/j.jcat.2023.115279. (院新闻报道:https://dwz.win/a7yT)
2. Luo, Z.; Peng, J.; Mu, Y.; Sun, L.; Zhu, Z.; Liu, Z.* Design of Cr-PNP catalysts for ethylene tri-/tetramerization assisted by a data-driven approach. Journal of Catalysis2023, 428. DOI: 10.1016/j.jcat.2023.115127.
3. Peng, J.; Zhu, M.; Chen, L.; Liu, Z.* Unravelling the chain growth mechanism in Cr/NNN-catalysed ethylene oligomerization. Catalysis Science & Technology2023 (封面文章). DOI: 10.1039/d3cy00954h. (RSC公众号推送:https://dwz.win/a7yU)
4. Liu, Z.; Qiu, P.; Sun, H.; Sun, L.; Zeng, Z.; Liu, Z.* Oxygen effect on the synthesis of vinyl acetate on Pd (100) and Pd/Au (100) surfaces: A periodic DFT study. Molecular Catalysis2023, 547. DOI: 10.1016/j.mcat.2023.113337.
5. Ding, X.; Mu, Y.; Zhu, Y.; Guo, X.; Liu, K.; Sun, L.; Liu, Z.* Mechanistic insight into the carboxylic derivatives formation from CO2 and ethylene over iron(0)-based catalyst. Molecular Catalysis2023, 541, 113084. DOI: 10.1016/j.mcat.2023.113084.
6. Zhu, Y.; Mu, Y.; Sun, L.; Zeng, Z.; Liu, Z.* Mechanistic study on the formation of the alkyl acrylates from CO2, ethylene and alkyl iodides over nickel-based catalyst. Phys. Chem. Chem. Phys.2023, 25 (36), 24733-24744. DOI: 10.1039/d3cp02943c.
7. Guo, X.; Liu, Z.*; Fan, Z.*; Liu, B.* New Insights into the Nature of Ti(II) and Ti(III) Active Sites in the Heterogeneous Ziegler–Natta Catalyst.J Phys Chem C2023, 127 (12), 5720-5730. DOI: 10.1021/acs.jpcc.2c08288.
8. Guan, Z.; Zhang, J.; Zhou, W.; Zhu, Y.; Liu, Z.*; Zhang, Y.*; Zhang, Y. Mechanistic Details of the Titanium-Mediated Polycondensation Reaction of Polyesters: A DFT Study. Catalysts2023, 13 (10). DOI: 10.3390/catal13101388.
9. Zhang, H.; Zhang, Z.; Cai, Z.*; Li, M.*; Liu, Z.*, Influence of Silica-Supported Alkylaluminum on Heterogeneous Zwitterionic Anilinonaphthoquinone Nickel and Palladium-Catalyzed Ethylene Polymerization and Copolymerization with Polar Monomers. ACS Catalysis2022, 12(15), 9646–9654. DOI: 10.1021/acscatal.2c02705
10. Guo, X.; Shao, Y.; Luo, J.; Liu, Z.*; Liu, B.*, The atomic defects on the (104) and (110) surfaces of the MgCl2-supported Ziegler-Natta Catalyst: a periodic DFT study. Catalysis Science & Technology2022, 12, 6761-6770. DOI: 10.1039/d2cy01365g
11. Zhong, X. Q.; Liu, L.; Guo, X.; Sun, L.; Liu, B. P.; Liu, Z.*, Cr/PCCP-catalysed selective ethylene oligomerization: analysis of various conformations and the hemilabile methoxy group. Catalysis Science & Technology 2022, 12, 5586-5596. DOI: 10.1039/d2cy01219g
12. Sun, H.; Qiu, P.*; Yang, Y.; Liu, J.; Zhang, L.; Liu, Z.*, Molecular insights into the vinyl acetate synthesis on Pd/Au (1 1 1) Surface: Effects of potassium ion. Applied Surface Science 2022, 571, 151297. DOI: 10.1016/j.apsusc.2021.151297
13. Qiu, P.; Sun, H.*; Yang, Y.; Liu, J.; Liu, Z.*, Molecular insights into the effects of N-doping on synthesis of vinyl acetate over carbon-supported zinc acetate. Catalysis Communications2022, 170, 106490. DOI: 10.1016/j.catcom.2022.106490
14. Zhu, Y.; Guo, X.; Ding, X.; Sun, L.; Zhang, M.; Liu, Z.*, Understanding the acrylates formation from CO2 and ethylene over Ni- and Pd-based catalysts: A DFT study on the effects of solvents, methyl halides, and ligands. Molecular Catalysis2022, 518, 112108. DOI: 10.1016/j.mcat.2021.112108
15. Wang, J.; Liu, C.; Cao, L.; Xiong, Y.; Ye, J.; Liu, Z.*; Cheng, R.*, Theoretical investigation of mechanism and ligand effects on half-sandwich iridium complexes for direct reductive amination. Molecular Catalysis 2022, 517, 112050. DOI: 10.1016/j.mcat.2021.112050
16. Zeng, F.; Guo, X.; Sun, L.*; He, X.; Zeng, Z.; Liu, Z.*, Non-isothermal crosslinking of ethylene vinyl acetate initiated by crosslinking agents: kinetic modelling. RSC Advances2022, 12 (24), 15623-15630. DOI: 10.1039/d2ra01994a
17. Guo, X.; Cui, L.; Yi, J.; Liu, Z.*; Liu, B.*, Understanding the Role of Sulfonyl Amine Donors in Propylene Polymerization Using MgCl2-Supported Ziegler–Natta Catalyst. Journal of Physical Chemistry C2022., 126(20), 8655-8666. DOI: 10.1021/acs.jpcc.2c02566
18. Chen, Y.; Qiu, P.; Sun, H.; Sun, L.; Liu, Z.*, Mechanistic aspects of the Pd(OAc)n (n=1–3) catalyzed ethylene acetoxylation: A density functional theory study. Applied Organometallic Chemistry2022. 36(10), e6860. DOI:10.1002/aoc.6860
19. Wang, Z.; Liu, L.; Ma, X.; Liu, Y.; Mi, P.; Liu, Z.*; Zhang, J.*, Effect of an additional donor on decene formation in ethylene oligomerization catalyzed by a Cr/PCCP system: a combined experimental and DFT study. Catalysis Science & Technology 2021, 11 (13), 4596-4604.
20. Zou, C., Yang L., Zhang L., Liu C., Ma Y., Song G., Liu Z.*, Cheng R.* and Ye J.* Enantioselective Vinylogous Conia-Ene Reaction Catalyzed by a Disilver(I)/Bisdiamine Complex. ACS Catalysis, 2021, 11(12): 6865-6871.
21. Liu, L.; Liu, Z.*; Cheng, R.; He, X.; Liu, B.*, Ligand-Induced Product Switching between 4-Methyl-1-pentene and 2-Methyl-1-pentene in Bis(imino)pyridine/V(III)-Catalyzed Propylene Dimerization: Cossee–Arlman Versus Metallacycle Mechanism. Organometallics 2021, 40 (11), 1682-1691.
22. Liu, K.; Liu, Z.*; Cheng, R.; He, X.; Liu, B.*, Mechanistic study of vanadium-modified and sulfation-modified Phillips catalyst. Molecular Catalysis 2021, 513, 111777.
23. Liu, K.; Liu, Z.*; Cheng, R.; He, X.; Liu, B.*, Mechanistic Studies of Reduction and Initiation over the Vanadium-Oxide Polyethylene Catalyst. Journal of Physical Chemistry C 2021, 125 (4), 2393-2402.
24. Guo, X.; Cui, L.; Wang, Y.; Yi, J.; Sun, J.; Liu, Z.*; Liu, B.*, Mechanistic Study on Effect of Electron Donors in Propylene Polymerization Using the Ziegler–Natta Catalyst. Journal of Physical Chemistry C 2021, 125 (16), 8533-8542.
代表性项目
1.2023企业技术开发项目,名称:《乙烯三聚催化体系小试制备技术开发》
2.2023企业技术开发项目,名称:《乙烯选择性齐聚合成线性α-烯烃》
3.2023企业技术开发项目,名称:《黄精寡糖和PROVTA 2.0作用信号通路的理论研究》
4.2022企业技术开发项目,名称:《高纯度2,6-萘二甲酸小试技术开发》
5.2022企业技术开发项目,名称:《2-甲基-6-乙酰基萘技术开发》
6.2021 国家自然科学基金,名称:《基于机器学习的乙烯选择性齐聚催化剂设计与开发》
7.2018 上海市浦江人才项目,名称:《CO2/不饱和烃制备羧酸及衍生物催化体系的分子设计》
8.2016 企业合作项目,名称:《丙烯聚合过程关键组分作用机理研究与分子设计》
9.2014 企业合作项目,名称:《高活性低分子量聚异丁烯的开发研究》
10.2013 国家自然科学基金,名称:《电子自旋交叉对铬系催化烯烃聚合反应的拟实研究》
11.2013 博士后基金,名称:《铬系催化乙烯齐聚、聚合反应中电子自旋交叉的基础研究》